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Methanesulfinylation of Benzyl Halides with Dimethyl Sulfoxide.
Fu, Duo; Dong, Jun; Du, Hongguang; Xu, Jiaxi.
Afiliação
  • Fu D; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry , Beijing University of Chemical Technology , Beijing 100029 , People's Republic of China.
  • Dong J; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry , Beijing University of Chemical Technology , Beijing 100029 , People's Republic of China.
  • Du H; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry , Beijing University of Chemical Technology , Beijing 100029 , People's Republic of China.
  • Xu J; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry , Beijing University of Chemical Technology , Beijing 100029 , People's Republic of China.
J Org Chem ; 85(4): 2752-2758, 2020 02 21.
Article em En | MEDLINE | ID: mdl-31873024
ABSTRACT
A phenyltrimethylammonium tribromide-mediated nucleophilic substitution/oxygen transformation reaction of benzyl halides with DMSO has been developed. In this transition-metal-free reaction, DMSO acts as not only a solvent but also a "S(O)Me" source, thus providing a convenient method for the efficient and direct synthesis of various benzyl methyl sulfoxides.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article