A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides.
Chem Commun (Camb)
; 56(12): 1815-1818, 2020 Feb 11.
Article
em En
| MEDLINE
| ID: mdl-31950941
ABSTRACT
The first example of visible light promoted fluoroalkylation reactions initiated via noncovalent interactions between acetone and fluoroalkyl iodides is presented. The reaction system features synthetic simplicity, mild reaction conditions without any photoredox catalyst, and high functional group tolerance. A wide range of substrate scopes such as alkenes, alkynes and (hetero)arenes were all compatible with the reaction system.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article