New hybridization coupling mechanism and enhanced sensitivity in a Cu2-xS@Au nanoparticle dimer.

ABSTRACT

To improve the refractive index sensitivity of a localized surface plasmon resonance (LSPR) sensor, we employ a new interparticle hybridization plasmon coupled resonance in a semiconductor-metal (Cu2-xS@Au) core-shell nanoparticle dimer (SMCSND), where the refractive index sensitivity can be improved by the generation of a tunable dual-band absorption spectrum at visible and near-infrared wavelengths. Owing to two LSPRs in different wavelength regions supported by the metal shell and semiconductor core, for the first time, we theoretically demonstrate that the new interparticle hybridization plasmon coupled mechanism in semiconductor-metal core-shell nanoparticle dimer depends not only on interparticle separation gap, but also on the nanoparticle shell thickness t. Electromagnetic model analysis reveals that there are two plasmon modes (Mode A and Mode C) associated with the interparticle hybridization plasmon coupled resonance, where the Mode C shows high sensitivity and figure of merit (FoM) to changes in the background dielectric medium. The tunability of the induced interparticle hybridization plasmon coupled resonance with different the separation distance and shell thickness can change the sensitivity and FoM of LSPR sensor in the visible to near-infrared region, which has broad application prospects.