Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions.
Chem Commun (Camb)
; 56(54): 7491-7494, 2020 Jul 11.
Article
em En
| MEDLINE
| ID: mdl-32497158
ABSTRACT
The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.
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MEDLINE
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En
Ano de publicação:
2020
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Article