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An unsymmetrical binuclear iminopyridine-iron complex and its catalytic isoprene polymerization.
Wang, Liang; Wang, Xiaowu; Hou, Hongbin; Zhu, Guangqian; Han, Zhenyu; Yang, Weiying; Chen, Xiao; Wang, Qinggang.
Afiliação
  • Wang L; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn.
  • Wang X; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn.
  • Hou H; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn.
  • Zhu G; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn and Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, B
  • Han Z; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn and Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, B
  • Yang W; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn and Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, B
  • Chen X; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn.
  • Wang Q; Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China. chenxiao@qibebt.ac.cn wangqg@qibebt.ac.cn.
Chem Commun (Camb) ; 56(62): 8846-8849, 2020 Aug 04.
Article em En | MEDLINE | ID: mdl-32633282
A series of chloride-bridged unsymmetrical mixed Fe(ii)-HS/Fe(ii)-LS binuclear structures has been prepared and characterized. Upon activation with MAO, highly efficient catalytic polymerization of isoprene was achieved, delivering an ultra-high molecular weight (catalyst loading = 2.5 ppm, Mn = 1.8 × 106 g mol-1, Mw/Mn = 1.4).
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article