A Review on Additives-assisted Ultrasound for Organic Pollutants Degradation.

ABSTRACT

In the past 2 decades, considerable attentions have been paid to the sonochemical advanced oxidation processes (SAOPs) in the fields of pollutants removal. SAOPs are powerful methods for refractory pollutants degradation due to the free radicals (e.g., •OH and •H) generated by water pyrolysis and extremely high temperature and pressure in and around cavitation bubbles. Reports on various additives for the improvement of sonochemical pollutants degradation including oxidants, inorganic anions, etc. have been made. This paper presents a comprehensive review on the ultrasound (US) alone and sono-hybrid systems for various pollutants degradation. In this paper, the degradation efficiency of various pollutants in sono-hybrid systems are elucidated in detail, and particular emphasis is placed on the reaction mechanism of additives in US for the enhancement of pollutants degradation. The problems on the applications of the current sono-hybrid systems are identified and discussed, and the outlooks for further in-depth studies on the challenges and some research needs for the applications of SAOPs for the removal of organic pollutants from aquatic systems are made at the end.