A valence tautomeric cobalt-dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides.
Dalton Trans
; 49(48): 17532-17536, 2020 Dec 22.
Article
em En
| MEDLINE
| ID: mdl-33300528
ABSTRACT
Here, we synthesized a valence tautomeric cobalt-dioxolene complex featuring a protected anchoring group. At room temperature, the complex reveals a nearly pure low-spin-Co(iii)-catecholate state in the solid state, but a nearly pure high-spin-Co(ii)-semiquinonate state in toluene solution. Thermal switchability of the complex in solution and in the solid state is investigated.
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MEDLINE
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En
Ano de publicação:
2020
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Article