Copper-Catalyzed Oxidative Cleavage of the C-C Bonds of ß-Alkoxy Alcohols and ß-1 Compounds.
ACS Omega
; 5(49): 31684-31691, 2020 Dec 15.
Article
em En
| MEDLINE
| ID: mdl-33344820
ABSTRACT
Copper-catalyzed aerobic oxidation conditions were employed to promote the C-C bond cleavage of ß-alkoxy alcohols and ß-1 compounds (lignin model compounds). Besides these compounds, various 1,2 and 1,3-diols were successfully converted to aldehydes. We propose the Cu(I)-catalyzed mechanism explaining the C-C cleavage of these 1,2 and 1,3-dihydroxy compounds and ß-alkoxy alcohols based on XPS data. Although our reaction conditions do not include large excess of bases and elaborated ligand-modified catalysts, copper salts with/without Me-TBD show good catalytic activities for C-C bond cleavage of various lignin model compounds.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article