New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2'-Bis(aminomethyl)-1,1'-binaphthyl.

Sato, Yasuhiro; Kawata, Yuichi; Yasui, Shungo; Kayaki, Yoshihito; Ikariya, Takao

Sato, Yasuhiro; Kawata, Yuichi; Yasui, Shungo; Kayaki, Yoshihito; Ikariya, Takao.

Afiliação

Sato Y; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-E4-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
Kawata Y; Hazardous Materials Laboratory, Research and Development Division, National Research Institute of Fire and Disaster, Jindaiji-higashimachi 4-35-3, Chofu, Tokyo 182-8508, Japan.
Yasui S; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-E4-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
Kayaki Y; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-E4-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
Ikariya T; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1-E4-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.

Molecules ; 26(4)2021 Feb 22.

Article em En | MEDLINE | ID: mdl-33671758

Assuntos

Compostos Aza/química; Complexos de Coordenação/química; Irídio/química; Naftalenos/química; Complexos de Coordenação/síntese química; Conformação Molecular

Palavras-chave

1,1-binaphthyl; asymmetric transfer hydrogenation; axial chirality; bifunctional catalyst; cyanation; cyclometalation; dinuclear complex; iridacycle; metal-ligand cooperation

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Aza / Complexos de Coordenação / Irídio / Naftalenos Idioma: En Ano de publicação: 2021 Tipo de documento: Article

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