Bamboo-like π-Nanotubes with Tunable Helicity and Circularly Polarized Luminescence.

ABSTRACT

We report the fabrication of an exotic bamboo-like π-nanotube via the hierarchical self-assembly of a dipeptide-substituted naphthalenediimide gelator with tunable helicity and circularly polarized luminescence (CPL). It was found that in the presence of trifluoroacetic acid (TFA) the gelator molecules self-assembled into a bamboo-like π-nanotube, which is composed of truncated nanocones and CPL active. When defining the diameter ratio of the lower to upper edge of each nanocone as a parameter to express the helicity of different nanotubes, it was found that both the helicity and CPL of these nanotubes can be adjusted by the amount of TFA. Moreover, the helicity of the nanotube can be conveyed to the achiral quantum dots (QDs) and produce a hybrid nanotube/QDs CPL active materials with adjustable dissymmetry factor. This work finds a new type self-assembled bamboo-like π-nanotube and unveils their helicity and CPL control.