Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries.
ACS Nano
; 15(6): 9841-9850, 2021 Jun 22.
Article
em En
| MEDLINE
| ID: mdl-34033458
ABSTRACT
As one of the CO2 capture and utilization technologies, Li-CO2 batteries have attracted special interest in the application of carbon neutral. However, the design and fabrication of a low-cost high-efficiency cathode catalyst for reversible Li2CO3 formation and decomposition remains challenging. Here, guided by theoretical calculations, CO2 was utilized to activate the catalytic activity of conventional nitrogen-doped graphene, in which pyridinic-N and pyrrolic-N have a high total content (72.65%) and have a high catalytic activity in both CO2 reduction and evolution reactions, thus activating the reversible conversion of Li2CO3 formation and decomposition. As a result, the designed cathode has a low voltage gap of 2.13 V at 1200 mA g-1 and long-life cycling stability with a small increase in the voltage gap of 0.12 V after 170 cycles at 500 mA g-1. Our work suggests a way to design metal-free catalysts with high activity that can be used to activate the performance of Li-CO2 batteries.
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MEDLINE
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En
Ano de publicação:
2021
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Article