Study of hydrolytic kinetics of the hexachlorostannate anion by two-dimensional 119 Sn exchange spectroscopy.
Magn Reson Chem
; 27(9): 836-840, 1989 Sep.
Article
em En
| MEDLINE
| ID: mdl-34034437
ABSTRACT
Two-dimensional 119 Sn exchange spectroscopy was applied to study the hydrolytic kinetics of the hexachloro-stannate anion, SnCl6 2- . Two 119 Sn exchange spectra for SnCl4 · 5H2 O solutions with various HCl concentrations are presented. Magnetization exchanges, which are related to the hydrolysis processes, occur in the SnCl6 2- hydrolysis series. The exchange rate constants, the hydrolysis rate constants and the hydrolysis equilibrium constants were evaluated.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
1989
Tipo de documento:
Article