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Iron-catalyzed alkylation of carbazole derivatives via hydroarylation of styrenes.
Xiao, En-Kai; Wu, Xian-Tao; Ma, Feng; Miao, Le-Wei; Jiang, Yi-Jun; Chen, Peng.
Afiliação
  • Xiao EK; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
  • Wu XT; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
  • Ma F; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
  • Miao LW; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
  • Jiang YJ; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
  • Chen P; School of Materials Science and Chemical Engineering, Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, P. R. China. jiangyijun@nbu.edu.cn chenpeng@nbu.edu.cn.
Chem Commun (Camb) ; 57(58): 7148-7151, 2021 Jul 20.
Article em En | MEDLINE | ID: mdl-34184010
ABSTRACT
The first direct and selective 3,6-di-alkylation of carbazoles via iron-catalyzed hydroarylation of styrenes is demonstrated. This simple, general and efficient method could deliver a wide range of di-benzyl-carbazoles with high chemo- and regio-selectivity at room temperature in up to 96% yield with no need for a noble-metal catalyst, directing group or additives.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2021 Tipo de documento: Article