Revealing Ammonia Quantification Minefield in Photo/Electrocatalysis.
Angew Chem Int Ed Engl
; 60(40): 21728-21731, 2021 09 27.
Article
em En
| MEDLINE
| ID: mdl-34328664
ABSTRACT
Photo/electrocatalytic ammonia synthesis has recently developed fast while the ammonia yields over state-of-the-art photo/electrocatalysts are still very moderate. Such low concentration of synthesized NH3 brings about a challenge to the reliable quantification of the product in photo/electrocatalysis. Notably, we found that the quantitative detection of ammonia concentration below 0.2 ppm is error-prone, which is likely the case happening in the majority of photo/electrocatalytic NH3 synthesis, thus arising concerns about the rationality and accuracy for low-concentration ammonia quantification in these processes. Herein, we discuss the methodology used and analyze the reliability of various detection methods for the detection of trace ammonia in aqueous media. The challenges facing the detection of low concentration of ammonia in photo/electrocatalysis can be overcome by integration with multiple detection methods. According to the data presented, we also propose an effective criterion for precise quantification of ammonia, avoiding the unreasonable comparisons in photo/electrocatalytic ammonia synthesis.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2021
Tipo de documento:
Article