Bio-synthesized Cu-ZnO hetro-nanostructure for catalytic degradation of organophosphate chlorpyrifos under solar illumination.

ABSTRACT

In present study, a simple, effective and rapid green method using leaf extract of Melia azedarach was explored for the synthesis of Cu-ZnO nano heterojunction particles. The leaf extract of Melia azedarach acts as a reducing agent and prevents the agglomeration of nanoparticles. Different standard analytical techniques were used to study the morphology and size of synthesized nanocomposite. The efficiency of the synthesized material was tested as a photocatalyst for the degradation of simulated wastewater having chlorpyriphos pesticide. The different factors have been investigated such as pH of the solution, catalyst dosage and conact time. Approximately, 81% of chlorpyrifos was degraded after 240 min of solar illumination. The generation of hydroxyl radicals at the catalysts surface owing to photo-irradiation contributed to the chlorpyrifos degradation. The maximum photo-degradation (91%) of pesticides was observed at 6.0 pH. The pathway for the degradation of chlorpyriphos has been checked by LC-MS and this hinting the absence of any harmfull side product. The COD removal and TOC was found to be 32.4% and 28.5%, respectively. The photodegradation of chlorpyriphos using Cu-ZnO nanocomposite was followed the pseudo-first-order kinetic with higher value of regressiuon coefficient (0.99).