A new organic-inorganic compound, ethyl-enedi-ammonium hexa-chlorido-stannate(IV) p-anisaldehyde disolvate.
Acta Crystallogr E Crystallogr Commun
; 77(Pt 7): 696-699, 2021 Jul 01.
Article
em En
| MEDLINE
| ID: mdl-34513013
ABSTRACT
The asymmetric unit of the title organic-inorganic hybrid complex [systematic name ethane-1,2-diaminium hexa-chlorido-stannate(IV)-4-meth-oxy-benz-alde-hyde (1/2)], (C2H10N2)[SnCl6]·2C8H8O2, contains one half of an ethyl-enedi-ammonium cation, one half of an [SnCl6]2- anion and one p-anisaldehyde mol-ecule. Both the organic cation and the quasi-regular octa-hedral inorganic anion are located about inversion centres. The organic cations and [SnCl6]2- anions lie in layers parallel to the ac plane with p-anisaldehyde mol-ecules occupying the space between the layers. A network of classical N-Hâ¯Cl and N-Hâ¯O hydrogen bonds exists between the ethyl-enedi-ammonium cations and the [SnCl6]2- anions and p-anisaldehyde mol-ecules. These inter-actions, together with non-classical C-Hâ¯O inter-actions between the ethyl-enedi-ammonium cations and the p-anisaldehyde mol-ecules, serve to hold the structure together. The crystal studied was refined as a two-component twin.
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MEDLINE
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En
Ano de publicação:
2021
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Article