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Synthesis of lanthanide-doped strontium aluminate nanoparticles encapsulated in polyacrylonitrile nanofibres: photoluminescence properties for anticounterfeiting applications.
El-Newehy, Mohamed H; Kim, Hak Yong; Khattab, Tawfik A; Moydeen A, Meera; El-Naggar, Mehrez E.
Afiliação
  • El-Newehy MH; Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, Saudi Arabia.
  • Kim HY; Nano Convergence Engineering, Jeonbuk National University, Jeonju, Republic of Korea.
  • Khattab TA; Textile Research Division, National Research Center, (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
  • Moydeen A M; Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, Saudi Arabia.
  • El-Naggar ME; Textile Research Division, National Research Center, (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
Luminescence ; 37(1): 40-50, 2022 Jan.
Article em En | MEDLINE | ID: mdl-34551199
Photochromism has been applied as an interesting technique in order to improve the anticounterfeiting of commercial commodities. To build up a mechanically reliable anticounterfeiting nanocomposite, it has been vital to enhance the engineering process of the anticounterfeiting material. In the current study, we developed mechanically reliable and highly photoluminescent lanthanide-doped strontium aluminate nanoparticles (LSAN)/polyacrylonitrile (PAN) hybrid nanofibres successfully fabricated using an electrospinning technique for anticounterfeiting applications. The produced nanocomposite films exhibited ultraviolet-induced photochromic anticounterfeiting properties. To guarantee the transparency of the LSAN-PAN film, LSAN must be immobilized onto the nanoparticle size to allow better dispersion without aggregation in the polyacrylonitrile matrix. The LSAN-PAN nanofibrous film demonstrated absorbance intensity that exhibited at 354 nm and associated with an emission intensity at 424 nm. The produced LSAN-PAN films demonstrated an enhanced hydrophobicity when increasing the ratio of LSAN, without adversely influencing their native appearance and mechanical performance. Upon excitation with ultraviolet light, the translucent nanofibrous substrates exhibited fast and reversible photochromic activity to greenish-yellow without exhaustion. The nanofibrous films exhibited stretchability, transparency, flexibility, and ultraviolet light-induced photochromism at low cost. The current strategy can be considered as an efficient technique towards the development of various anticounterfeiting materials for a better market with economic and social values.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Elementos da Série dos Lantanídeos / Nanopartículas / Nanofibras Idioma: En Ano de publicação: 2022 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Elementos da Série dos Lantanídeos / Nanopartículas / Nanofibras Idioma: En Ano de publicação: 2022 Tipo de documento: Article