Achieving High-Performance 3D K+ -Pre-intercalated Ti3 C2 Tx MXene for Potassium-Ion Hybrid Capacitors via Regulating Electrolyte Solvation Structure.
Angew Chem Int Ed Engl
; 60(50): 26246-26253, 2021 Dec 06.
Article
em En
| MEDLINE
| ID: mdl-34590399
ABSTRACT
The development of high-performance anode materials for potassium-based energy storage devices with long-term cyclability requires combined innovations from rational material design to electrolyte optimization. A three-dimensional K+ -pre-intercalated Ti3 C2 Tx MXene with enlarged interlayer distance was constructed for efficient electrochemical potassium-ion storage. We found that the optimized solvation structure of the concentrated ether-based electrolyte leads to the formation of a thin and inorganic-rich solid electrolyte interphase (SEI) on the K+ -pre-intercalated Ti3 C2 Tx electrode, which is beneficial for interfacial stability and reaction kinetics. As a proof of concept, 3D K+ -Ti3 C2 Tx //activated carbon (AC) potassium-ion hybrid capacitors (PIHCs) were assembled, which exhibited promising electrochemical performances. These results highlight the significant roles of both rational structure design and electrolyte optimization for highly reactive MXene-based anode materials in energy storage devices.
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2021
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Article