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Reply to the 'Comment on "Revisiting π backbonding: the influence of d orbitals on metal-CO bonds and ligand red shifts"' by G. Frenking and S. Pan, Phys. Chem. Chem. Phys., 2019, 22, DOI: 10.1039/C9CP05951B.
Koch, Daniel; Chen, Yingqian; Golub, Pavlo; Manzhos, Sergei.
Afiliação
  • Koch D; Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore, 117575, Singapore.
  • Chen Y; Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore, 117575, Singapore.
  • Golub P; Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore, 117575, Singapore.
  • Manzhos S; Centre Énergie Matériaux Télécommunications, Institut National de la Recherche Scientifique, 1650, boulevard Lionel-Boulet, Varennes, QC J3X1S2, Canada. sergei.manzhos@emt.inrs.ca.
Phys Chem Chem Phys ; 22(9): 5380-5382, 2020 Mar 04.
Article em En | MEDLINE | ID: mdl-34661588
ABSTRACT
We respond to the comment by Pan and Frenking with regard to our investigation on transition and alkaline earth metal d orbital influence on their bonding to carbonyl ligands to clarify misconceptions. We do not consider the points raised in the comment as affecting our conclusions.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article