FeIII in a high-spin state in bis(5-bromosalicylaldehyde 4-ethylthiosemicarbazonato-&#954;3O,N1,S)ferrate(III) nitrate monohydrate, the first example of such a cationic FeIII complex unit.

Powell, Robyn E; Lees, Martin R; Tizzard, Graham J; Koningsbruggen, Petra J van

Fe^III in a high-spin state in bis(5-bromosalicylaldehyde 4-ethylthiosemicarbazonato-κ³O,N¹,S)ferrate(III) nitrate monohydrate, the first example of such a cationic Fe^III complex unit.

Powell, Robyn E; Lees, Martin R; Tizzard, Graham J; Koningsbruggen, Petra J van.

Afiliação

Powell RE; College of Engineering and Physical Sciences, School of Infrastructure and Sustainable Engineering, Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham, West Midlands, B4 7ET, UK.
Lees MR; Department of Physics, University of Warwick, Coventry, CV4 7AL, UK.
Tizzard GJ; National Crystallography Service, Chemistry, University of Southampton, Southampton, SO17 1BJ, UK.
Koningsbruggen PJV; College of Engineering and Physical Sciences, School of Infrastructure and Sustainable Engineering, Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham, West Midlands, B4 7ET, UK.

Acta Crystallogr C Struct Chem ; 78(Pt 1): 63-69, 2022 Jan 01.

Article em En | MEDLINE | ID: mdl-34982050

Palavras-chave

carbazone; crystal structure; high spin; iron(III); magnetic susceptibility; tautomerism

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Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2022 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2022 Tipo de documento: Article