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Two-dimensional Zr/Hf-hydroxamate metal-organic frameworks.
Lai, Qiuxue; Chu, Zhao-Qin; Xiao, Xinyi; Dai, Dejun; Song, Ting; Luo, Tian-Yi; Tang, Wenlei; Feng, Xuan; Zhang, Zhiyuan; Li, Tao; Xiao, Hai; Su, Jing; Liu, Chong.
Afiliação
  • Lai Q; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Chu ZQ; College of Chemistry, Sichuan University, Chengdu, 610064, China. jingsu@scu.edu.cn.
  • Xiao X; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Dai D; School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
  • Song T; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Luo TY; Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD 21218, USA.
  • Tang W; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Feng X; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Zhang Z; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
  • Li T; School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China.
  • Xiao H; Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Su J; College of Chemistry, Sichuan University, Chengdu, 610064, China. jingsu@scu.edu.cn.
  • Liu C; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China. liuchong@scu.edu.cn.
Chem Commun (Camb) ; 58(22): 3601-3604, 2022 Mar 15.
Article em En | MEDLINE | ID: mdl-35103744
ABSTRACT
Novel two-dimensional kagome metal-organic frameworks with mononuclear Zr4+/Hf4+ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 µm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article