Air-Tolerant Reversible Complexation Mediated Polymerization (RCMP) Using Aldehyde.
Macromol Rapid Commun
; 43(10): e2200091, 2022 May.
Article
em En
| MEDLINE
| ID: mdl-35338552
ABSTRACT
An air-tolerant reversible complexation mediated polymerization (RCMP) technique, which can be carried out without prior deoxygenation, is developed. The system contains a monomer, an alkyl iodide initiating dormant species, air (oxygen), an aldehyde, N-hydroxyphthalimide (NHPI), and a base. Oxygen is consumed via the NHPI-catalyzed conversion of the aldehyde (RCHO) to a carboxylic acid (RCOOH). The generated RCOOH is further converted to a carboxylate anion (RCOO- ) by the base. The RCOO- generated in situ works as an RCMP catalyst; the polymerization proceeds with the monomer, alkyl iodide dormant species, and RCOO- catalyst. Thus, the system is not only air-tolerant but also does not require additional RCMP catalysts, which is a notable feature of this system. (NHPI is used as an oxidation catalyst for converting RCHO to RCOOH.) This technique is amenable to methyl methacrylate, butyl methacrylate, benzyl methacrylate, 2-hydroxyethyl methacrylate, and styrene, yielding polymers with relatively low-dispersity (Mw /Mn = 1.20-1.49), where Mw and Mn are the weight- and number-average molecular weights, respectively.
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Base de dados:
MEDLINE
Assunto principal:
Aldeídos
/
Iodetos
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article