Explicating the amino acid effects for methane storage in hydrate form.
RSC Adv
; 12(16): 10178-10185, 2022 Mar 25.
Article
em En
| MEDLINE
| ID: mdl-35424906
ABSTRACT
Methane emissions increase day by day into the atmosphere and influence global temperatures. The necessity to capture these emissions at the source point is a primary concern. Several methods/techniques are being adopted to capture these emissions. The methane hydrates could be a viable method among them. The present study exposes various amino acids' effects in methane hydrate formation. The formation temperatures are around â¼268 to 273 K except for l-cys, which is about â¼277 K. The required subcooling for hydrates to trigger is high and is increasing in the order l-thr > l-met > l-phe > l-val > l-cys. The methane hydrate conversion is high in the presence of nearly all the amino acids with methane uptake capacity of â¼80-85%, except l-thr, for which it is only 30% of the total uptake capacity. The side chain of l-thr comprises the hydroxyl group, making it a polar and uncharged amino acid. It is ascertained that hydroxyl groups alone can form hydrogen bonds with water, increasing the hydrophilicity and solubility of molecules, causing lesser conversion in the l-thr system. The gas uptake kinetics is faster in l-met and l-phe systems (t 90 â¼ 40 min), and sluggish kinetics is observed in l-cys, l-val, and l-thr systems. The investigations positively indicate using amino acids, l-met, l-phe, l-cys, and l-val as efficient materials for methane gas capture and storage in hydrate form, although not l-thr. Amino acids are readily dissolvable in water and could be easily pelletized for methane gas storage and transportation.
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MEDLINE
Idioma:
En
Ano de publicação:
2022
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Article