All-Inorganic Manganese-Based CsMnCl3 Nanocrystals for X-Ray Imaging.
Adv Sci (Weinh)
; 9(18): e2201354, 2022 06.
Article
em En
| MEDLINE
| ID: mdl-35466546
ABSTRACT
Lead-based halide perovskite nanomaterials with excellent optical properties have aroused great attention in the fields of solar cells, light-emitting diodes, lasing, X-ray imaging, etc. However, the toxicity of lead prompts researchers to develop alternatives to cut down the usage of lead. Herein, all-inorganic manganese-based perovskite derivatives, CsMnCl3 nanocrystals (NCs), with uniform size and morphology have been synthesized successfully via a modified hot-injection method. These NCs have a direct bandgap of 4.08 eV and a broadband emission centered at 660 nm. Through introducing modicum lead (1%) into the CsMnCl3 NCs, the photoluminescence intensity greatly improves, and the quantum yield (PLQY) increases from 0.7% to 21%. Furthermore, the CsMnCl31%Pb NCs feature high-efficiency of X-ray absorption and radioluminescence, which make these NCs promising candidates for X-ray imaging.
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MEDLINE
Assunto principal:
Nanopartículas
/
Manganês
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article