Synthesis of d-glyco-alkynone derivatives via carbonylative Sonogashira reaction.
RSC Adv
; 9(17): 9468-9474, 2019 Mar 22.
Article
em En
| MEDLINE
| ID: mdl-35520747
ABSTRACT
A carbonylative Sonogashira coupling approach to the synthesis of glyco-alkynones is described. Eighteen examples were obtained in moderate do nearly quantitative yields under mild conditions employing Mo(CO)6 as a safe carbon monoxide source. Functionalization of the alkynyl moiety via cycloaddition with organic azides provided six examples of glyco-triazoles.
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MEDLINE
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En
Ano de publicação:
2019
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Article