C-N Bond Forming Radical Rebound Is the Enantioselectivity-Determining Step in P411-Catalyzed Enantioselective C(sp<sup>3</sup>)-H Amination: A Combined Computational and Experimental Investigation.

Mai, Binh Khanh; Neris, Natalia M; Yang, Yang; Liu, Peng

C-N Bond Forming Radical Rebound Is the Enantioselectivity-Determining Step in P411-Catalyzed Enantioselective C(sp³)-H Amination: A Combined Computational and Experimental Investigation.

Mai, Binh Khanh; Neris, Natalia M; Yang, Yang; Liu, Peng.

Afiliação

Mai BK; Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States.
Neris NM; Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States.
Yang Y; Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States.
Liu P; Biomolecular Science and Engineering (BMSE) Program, University of California, Santa Barbara, California 93106, United States.

J Am Chem Soc ; 144(25): 11215-11225, 2022 06 29.

Article em En | MEDLINE | ID: mdl-35583461

Assuntos

Hidrogênio; Aminação; Biocatálise; Catálise; Ciclização; Hidrogênio/química; Estereoisomerismo

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Hidrogênio Idioma: En Ano de publicação: 2022 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Hidrogênio Idioma: En Ano de publicação: 2022 Tipo de documento: Article