Facile Preparation of Silk Fabrics with Enhanced UV Radiation Shielding and Wrinkle Resistance by Cross-Linking Light-Responsive Copolymers.

ABSTRACT

Enhanced UV radiation shielding is realized by cross-linking the light-responsive copolymer poly(di(ethylene glycol)methyl ether methacrylate-co-oligo(ethylene glycol)methyl ether methacrylate-co-ethylene glycol methacrylate-co-6-(4-phenylazo-phenoxy)hexyl methacrylate), abbreviated as PMOEA, with silk fabrics. Owing to the existence of the azobenzene component in 6-(4-phenylazo-phenoxy)hexyl methacrylate, UV radiation can be significantly absorbed in an aqueous PMOEA solution by the trans-cis isomerization of azobenzene. After immobilization onto the silk fabrics by the cross-linker 1,2,3,4-butanetetracarboxylic acid, the cross-linked copolymer-coated silk fabrics present an enhanced capability of UV radiation absorption. More than 70% of the UV radiation is efficiently shielded by the cross-linked copolymer-coated silk fabrics, which is double that of the original silk fabrics. Considering the limited amount of the light-responsive copolymer applied (5 wt %), UV protection is successfully realized for the silk fabrics. In addition, the cross-linked copolymer layer also forms covalent bonds with the hydroxyl and amino groups on the silk fabrics. Wrinkles on the silk fabrics, typically caused by the movement of the silk chains, are suppressed by the formed covalent bonds, significantly hindering such chain movement. Therefore, the wrinkle resistance capability is also improved by cross-linking PMOEA on silk fabrics. As the glass transition temperature of the copolymer is lower than room temperature, the hand feel of silk fabrics is not affected by the cross-linking layer. Based on these advantages, the cross-linked copolymer-coated silk fabrics can be used for light clothes to shield against UV radiation from the sun during outdoor activities in summer.