Asymmetrically Substituted Phospholes as Ligands for Coinage Metal Complexes.
Molecules
; 27(11)2022 May 24.
Article
em En
| MEDLINE
| ID: mdl-35684306
ABSTRACT
A series of coinage metal complexes asymmetrically substituted 2,5-diaryl phosphole ligands is reported. Structure, identity, and purity of all obtained complexes were corroborated with state-of-the-art techniques (multinuclear NMR, mass spectrometry, elemental analysis, X-ray diffraction) in solution and solid state. All complexes obtained feature luminescence in solution as well as in the solid state. Additionally, DOSY-MW NMR estimation experiments were performed to achieve information about the aggregation behavior of the complexes in solution allowing a direct comparison with their structures observed in the solid state.
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MEDLINE
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En
Ano de publicação:
2022
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Article