Synthesis of Mixed Arylalkyl Tertiary Phosphines via the Grignard Approach.
Molecules
; 27(13)2022 Jul 01.
Article
em En
| MEDLINE
| ID: mdl-35807497
ABSTRACT
Trialkyl and triaryl phosphines are important classes of ligands in the field of catalysis and materials research. The wide usability of these low-valent phosphines has led to the design and development of new synthesis routes for a variety of phosphines. In the present work, we report the synthesis and characterization of some mixed arylalkyl tertiary phosphines via the Grignard approach. A new asymmetric phosphine is characterized extensively by multi-spectroscopic techniques. IR and UV-Vis spectra of some selected compounds are also compared and discussed. Density functional theory (DFT)-calculated results support the formation of the new compounds.
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MEDLINE
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Fosfinas
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En
Ano de publicação:
2022
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Article