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Periodate anions as a halogen bond donor: formation of anion⋯anion dimers and other adducts.
Calabrese, Miriam; Pizzi, Andrea; Daolio, Andrea; Frontera, Antonio; Resnati, Giuseppe.
Afiliação
  • Calabrese M; NFMLab, Department Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131 Milano, Italy. andrea.pizzi@polimi.it.
  • Pizzi A; NFMLab, Department Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131 Milano, Italy. andrea.pizzi@polimi.it.
  • Daolio A; NFMLab, Department Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131 Milano, Italy. andrea.pizzi@polimi.it.
  • Frontera A; Department Chemistry, Universitat de les Illes Balears, Crta, de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain. toni.frontera@uib.es.
  • Resnati G; NFMLab, Department Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, via L. Mancinelli 7, I-20131 Milano, Italy. andrea.pizzi@polimi.it.
Chem Commun (Camb) ; 58(66): 9274-9277, 2022 Aug 16.
Article em En | MEDLINE | ID: mdl-35904031
Single crystal X-ray analyses show that iodine in pyridinium periodates acts as a halogen bond (HaB) donor forming short and almost linear contacts with neutral and anionic electron donors. A combination of QTAIM and NCIplot computational tools proves the attractive nature of these contacts.
Assuntos

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Halogênios / Iodo Idioma: En Ano de publicação: 2022 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Halogênios / Iodo Idioma: En Ano de publicação: 2022 Tipo de documento: Article