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Direct Transformation of Nitrogen-Containing Methylheteroarenes to Heteroaryl Nitrile by Sodium Nitrite.
Jiang, Chenhui; Chen, Yuqin; Gao, Pan; Zhang, Shuwei; Jia, Xiaodong; Yuan, Yu.
Afiliação
  • Jiang C; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
  • Chen Y; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
  • Gao P; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
  • Zhang S; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
  • Jia X; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
  • Yuan Y; School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China.
Org Lett ; 24(34): 6341-6345, 2022 09 02.
Article em En | MEDLINE | ID: mdl-35993577
ABSTRACT
The cyanation reaction of methylheteroarenes with acetyl chloride and sodium nitrite via the radical process in high yields is reported. According to the control experiments, the reaction mechanism underwent radical progress. It is very useful in the pharmacy industry due to its metal-free and easy treatment conditions.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Nitrilas / Nitrogênio Idioma: En Ano de publicação: 2022 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Nitrilas / Nitrogênio Idioma: En Ano de publicação: 2022 Tipo de documento: Article