Fabrication of AQ2S/GR composite photosensitizer for the simulated solar light-driven degradation of sulfapyridine.
Environ Sci Ecotechnol
; 8: 100111, 2021 Oct.
Article
em En
| MEDLINE
| ID: mdl-36156993
ABSTRACT
Chlorination has been intensively investigated for use in water disinfection and pollutant elimination due to its efficacy and convenience; however, the generation and transportation of chlorine and hypochlorite are energy-consuming and complicated. In this study, a novel binary photosensitizer consisting of anthraquinone-2-sulfonate (AQ2S) and graphene was synthesized via a π-π stack adsorption method; this compound could allow for the chlorination of organic pollutants using on-site chlorine generation. In this photosensitive degradation process, sulfapyridine (SPY) was selected as a model pollutant and was decomposed by the reactive species (Cl2 â¢-, Cl⢠and O2 â¢-) generated during the photosensitive oxidation of chloride. The synthesized AQ2S/graphene exhibited superior activity, and the degradation rate of SPY was over 90 % after 12 h of visible light irradiation with a kinetic constant of 0.2034h-1. Results show that 20 mg AQ2S/GR at a 21 % weight percentage of AQ2S in a pH 7 SPY solution with 1 mol/L Cl- achieved the highest kinetics rate at 0.353 h-1. Free radical trapping experiments demonstrated that Cl2 â¢- and O2 â¢- were the dominant species involved in SPY decomposition under solar light. The reusability and stability of this composite were verified by conducting a cycle experiment over five successive runs. The capacity of photodegradation still remained over 90 % after these 5 runs. The current study provides an energy-efficient and simple-operational approach for water phase SPY control.
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MEDLINE
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En
Ano de publicação:
2021
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Article