Synthesis, crystal structure, and properties of methyl-substituted coronene amide analogue.
RSC Adv
; 12(40): 26411-26417, 2022 Sep 12.
Article
em En
| MEDLINE
| ID: mdl-36275098
ABSTRACT
A coronene amide analogue was synthesized in six steps using an improved method at the final biarylation step. The key to the progress of palladium-mediated biarylation involved the introduction of three methyl groups to suppress the undesired reaction and the use of tri-tert-butylphosphine as the ligand for palladium. Single-crystal X-ray analysis revealed that the core unit of the coronene analogue has a non-planar structure.
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MEDLINE
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En
Ano de publicação:
2022
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Article