Flow-through heterogeneous electro-Fenton system using a bifunctional FeOCl/carbon cloth/activated carbon fiber cathode for efficient degradation of trimethoprim at neutral pH.

ABSTRACT

The synthesis of multifunctional cathode with high-efficiency and stable catalytic activity for simultaneously producing and activating H2O2 is an effective way for promoting the performance of heterogeneous electro-Fenton process (HEF). In addition, accelerating mass transfer by adopting a flow-through reactor is also great importance because of its better utilization of catalysts and adequate contact of the contaminant with the oxidants generated on the electrode surface. Herein, a novel flow-through HEF (FHEF) system was designed for the degradation of trimethoprim (TMP) using bifunctional cathode with a sandwich structure FeOCl nanosheets loaded onto carbon cloth (CC) and activated carbon fiber (ACF) (FeOCl/CC/ACF). The cathode exhibited excellent performance in activating H2O2 for the in-situ generation of hydroxyl radicals (•OH). The electron spin resonance (ESR) measurements and radical quenching tests proved that the high production of •OH in the FHEF process was favorable to the high catalytic efficiency. 25 mg L-1 TMP was entirely degraded after 60 min, with the TOC removal of 62.6% (180 min) at pH 6.8, 9.0 mA cm-2, and flux rate 210 mL min-1. Moreover, the degradation rate still could reach 83% (60 min) after 10 cycles without obvious valence and crystal phase changes. Simultaneously, the current utilization rate has also been greatly enhanced, with an average current efficiency of 69.9% and a low energy consumption of 0.28 kWh kg-1. The reasonable degradation pathways for TMP were proposed based on the UPLC-QTOF-MS/MS results. Finally, the results of toxicological simulation showed a declining trend in the toxicity of the samples during TMP degradation. These results claim that the FeOCl/CC/ACF-FHEF system is an efficient and economical technology for the treatment of organic contaminants in effluents.