Entropy-Driven Ultrafast Ion Conduction Via Confining Organic Plastic Crystals in Ordered Nanochannels of Covalent Organic Frameworks.
Small
; 19(17): e2207831, 2023 Apr.
Article
em En
| MEDLINE
| ID: mdl-36670085
ABSTRACT
Low conductivity over a wide temperature region due to ultra-slow ion migration dynamics is a key issue in the field of solid-state electrolytes (SSE), which needs to be solved and improved. Covalent organic frameworks (COFs), a rapidly growing class of porous crystalline materials, emerge as a new research hotspot in the field of SSEs. This is due to their homogeneously dispersed sites and well-defined pathways for ion diffusion, demonstrating great advantages over conventional non-porous solids. Herein, a composite solid electrolyte by confining organic ionic plastic crystal (OIPC) in the 1D ordered nanochannels of COFs as the host matrix for solid-state lithium-ion conduction, is reported. Due to the loss of coupling between PBu4 + cations and TFSI- anions, the cation-anion interaction is weakened; and thus, the lithium-ion transportation is facilitated. As a result, the COF-confining OIPC SSEs show ultra-high lithium-ion conductivity of 0.048 S cm-1 at 30 °C and 0.021 S cm-1 at the extremely low temperature of -30 °C. The dynamic origin of this fast ion conduction is characterized by differential scanning calorimetry (DSC), X-ray photoelectron spectroscopy (XPS), and variable temperature solid-state nuclear magnetic resonance (NMR) spectroscopy.
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MEDLINE
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En
Ano de publicação:
2023
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Article