A Zeolite-Like Metal-Organic Framework Based Membrane for Reverse Selective Hydrogen Separation and Butane Isomer Sieving.
Angew Chem Int Ed Engl
; 62(16): e202218842, 2023 Apr 11.
Article
em En
| MEDLINE
| ID: mdl-36762967
ABSTRACT
Here, the fabrication of a defect-free membrane that is based on a zeolite-like metal-organic framework (ZMOF) with the underlying ana topology is reported. The unique ana-ZMOF structure provides high degree of pore connectivity, which is reflected by the fast transport of gases. Prominently, it offers an optimum pore-aperture size, affording notable sieving selectivity for butane/isobutane, and optimal pore energetics for reverse CO2 /H2 separation. This emphasize the potential for the application of pure MOF membranes, paving the way to more sustainability of energy resources.
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MEDLINE
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En
Ano de publicação:
2023
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Article