Selective Valorization of Bio-derived Levulinic Acid and Its Derivatives into Hydrocarbons and Biochemicals by Using Hydrosilylation.
Chemistry
; 29(30): e202300119, 2023 May 26.
Article
em En
| MEDLINE
| ID: mdl-36896735
ABSTRACT
Herein we report an efficient hydrosilylation strategy to selectively defunctionalize biomass-derived levulinic acid into value-added chemicals such as pentane-1,4-diol, pentan-2-ol, 2-MTHF and C5 hydrocarbons by using cost-effective silanes and the commercially available catalyst B(C6 F5 )3 at room temperature. All reactions work well in chlorinated solvents but, as a greener alternative, most reactions can be run in toluene or solvent-less.
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MEDLINE
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En
Ano de publicação:
2023
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Article