Bioinspired Hydrophobicity Coupled with Single Fe-N4 Sites Promotes Oxygen Diffusion for Efficient Zinc-Air Batteries.

The poor oxygen diffusion and sluggish oxygen reduction reaction (ORR) kinetics at multiphase interfaces in the cathode suppress the practical application of zinc-air batteries. Developing effective strategies to tackle the issue is of great significance for overcoming the performance bottleneck but remains challenging. Here, a multiscale hydrophobic surface is designed on the iron single-atom catalyst via a gas-phase fluorination-assisted method inspired by the structure of gas-trapping mastoids on lotus leaves. The hydrophobic Fe-FNC attains a higher peak power density of up to 226 mW cm-2 , a long durability of up close to 140 h, and better cyclic durability of up to 300 cycles compared to the corresponding Pt/C-based Zn-air battery. Experiments and theoretical calculations indicate that the formed more triple-phase interfaces and exposed isolated Fe-N4 sites are proposed as the governing factors in boosting electrocatalytic ORR activity and remarkable cycling durability for Zn-air batteries.