Self-Assembly Monolayer Inspired Stable Artificial Solid Electrolyte Interphase Design for Next-Generation Lithium Metal Batteries.

ABSTRACT

Lithium metal is widely regarded as the "ultimate" anode for energy-dense Li batteries, but its high reactivity and delicate interface make it prone to dendrite formation, limiting its practical use. Inspired by self-assembled monolayers on metal surfaces, we propose a facile yet effective strategy to stabilize Li metal anodes by creating an artificial solid electrolyte interphase (SEI). Our method involves dip-coating Li metal in MPDMS to create an SEI layer that is rich in inorganic components, allowing uniform Li plating/stripping under a low overpotential over 500 cycles in carbonate electrolytes. In comparison, pristine Li metal shows a rapid increase in overpotential after merely 300 cycles, leading to failure soon after. Molecular dynamics simulations demonstrate that this uniform artificial SEI suppresses Li dendrite formation. We further demonstrated its enhanced stability pairing with LiFePO4 and LiNi1-x-yCoxMnyO2 cathodes, highlighting the proposed strategy as a promising solution for practical Li metal batteries.