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Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure.
Huang, Shuzhao; Zhu, Liang; Kruglov, Ivan; Yang, Yun; Yang, Zhihua; Pan, Shilie.
Afiliação
  • Huang S; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China.
  • Zhu L; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
  • Kruglov I; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China.
  • Yang Y; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
  • Yang Z; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China.
  • Pan S; Moscow Institute of Physics and Technology, 9 Institutsky Lane, Dolgoprudny 141700, Russia.
Inorg Chem ; 62(20): 7599-7604, 2023 May 22.
Article em En | MEDLINE | ID: mdl-37158437
Borates and fluorooxoborates are advanced optical materials with great potential applications in the ultraviolet (UV) and deep ultraviolet (DUV) regions. Herein, two new UV optical crystals K6B12O19F4 and K12B28O48 were synthesized. Among them, K6B12O19F4 has a rare disorder of BO3 and BO4 units, which is the first time this disordered type has been found in fluorooxoborates. In this paper, the properties of K6B12O19F4 and K12B28O48 were tested and calculated, and their crystal structures and structural evolution were carefully analyzed. In addition, the effects of metal cations size and F ions on the crystal structure were analyzed. This research enriches the structural chemistry of borates and fluorooxoborates, and provides experience for the design of new UV optical crystals.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article