Performance of biochar mixed cement paste for removal of Cu, Pb and Zn from stormwater.

Using biochar as a partial replacement of Portland cement in cementitious materials is a promising solution to mitigate negative environmental impacts. However, current studies in available literature primarily focus on the mechanical properties of composites made with cementitious materials and biochar. Therefore, this paper reports the effects of the type of biochar, the percentage of biochar addition, and the particle size of the biochar on the removal efficiency of Cu, Pb, and Zn, as well as the effect of contact time on the removal efficiency of Cu, Pb, and Zn, along with the compressive strength. The peak intensities of OH-, CO32- and Calcium Silicate Hydrate (Ca-Si-H) peaks increase with increasing biochar addition levels, reflecting increased hydration product formation. The reduction of particle size of biochar causes the polymerization of the Ca-Si-H gel. However, no significant changes were observed in heavy metal removal, irrespective of the percentage of biochar addition, the particle size of biochar, or the type of biochar added to the cement paste. Adsorption capacities above 19 mg/g, 11 mg/g and 19 mg/g for Cu, Pb and Zn were recorded in all composites at an initial pH of 6.0. The Pseudo second order model best described the kinetics of the Cu, Pb, and Zn removal. The rate of adsorptive removal increases with the decrease in the density of the adsorbents. Over 40% of Cu and Zn were removed as carbonates and hydroxides through precipitation, whereas over 80% of Pb removal was via adsorption. Heavy metals bonded with OH-, CO32- and Ca-Si-H functional groups. The results demonstrate that biochar can be used as a cement replacement without negatively impacting heavy metal removal. However, neutralization of the high pH is needed before safe discharge.