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Metal-mediated tunability of MOF-based optical modulators.
Kulachenkov, Nikita K; Orlioglo, Bogdan; Vasilyev, Eugene S; Povarov, Svyatoslav A; Agafontsev, Alexander M; Bachinin, Semyon; Shipilovskikh, Sergei; Lunev, Artem; Samsonenko, Denis G; Fedin, Vladimir P; Kovalenko, Konstantin A; Milichko, Valentin A.
Afiliação
  • Kulachenkov NK; School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
  • Orlioglo B; Chemical Science Program, KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia.
  • Vasilyev ES; Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia.
  • Povarov SA; School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
  • Agafontsev AM; Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia.
  • Bachinin S; Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russia.
  • Shipilovskikh S; School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
  • Lunev A; School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
  • Samsonenko DG; School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
  • Fedin VP; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia. k.a.kovalenko@niic.nsc.ru.
  • Kovalenko KA; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia. k.a.kovalenko@niic.nsc.ru.
  • Milichko VA; Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia. k.a.kovalenko@niic.nsc.ru.
Chem Commun (Camb) ; 59(66): 9964-9967, 2023 Aug 15.
Article em En | MEDLINE | ID: mdl-37501597
ABSTRACT
We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article