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A smart and visible way to switch the aromaticity of silicon(IV) phthalocyanines.
Ke, Mei-Rong; Chen, Zixuan; Shi, Jie; Wei, Ying; Liu, Hao; Huang, Shuping; Li, Xingshu; Zheng, Bi-Yuan; Huang, Jian-Dong.
Afiliação
  • Ke MR; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Chen Z; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Shi J; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Wei Y; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Liu H; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Huang S; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Li X; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Zheng BY; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
  • Huang JD; Fujian Provincial Key Laboratory of Cancer Metastasis Chemoprevention and Chemotherapy, College of Chemistry, Fuzhou University, Fuzhou 350108, China. jdhuang@fzu.edu.cn.
Chem Commun (Camb) ; 59(65): 9832-9835, 2023 Aug 10.
Article em En | MEDLINE | ID: mdl-37505224
Unlike traditional methods of modifying phthalocyanines (Pcs), we herein report a smart and visible way to switch the aromaticity of silicon(IV) phthalocyanines via a reversible nucleophilic addition reaction of the Pc skeleton induced by alkalis and acids, leading to an interesting allochroism phenomenon and the switching of photosensitive activities.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article