Coordination Engineering of Dual Co, Ni Active Sites in N-Doped Carbon Fostering Reversible Oxygen Electrocatalysis.
Inorg Chem
; 62(33): 13519-13529, 2023 Aug 21.
Article
em En
| MEDLINE
| ID: mdl-37562977
ABSTRACT
The development of affordable and non-noble-metal-based reversible oxygen electrocatalysts is required for renewable energy conversion and storage systems like metal-air batteries (MABs). However, the nonbifunctionality of most of the catalysts impedes their use in rechargeable MAB applications. Moreover, the loss of active sites also affects the long-term performance of the electrocatalyst toward oxygen electrocatalysis. In this work, we report a simplistic yet controllable chemical approach for the synthesis of dual transitional metals such as cobalt, nickel, and nitrogen-doped carbon (CoNi-NC) as bifunctional electrode materials for rechargeable zinc-air batteries (ZABs). The spatially isolated Ni-N4 and Co-N4 active units were rendered for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), respectively. The individual efficacy of both reversible reactions enables an ΔE value of â¼0.72 V, which outperforms several bifunctional electrocatalysts reported in the literature. The half-wave potential (E1/2) and overpotential were achieved at 0.83 V and 330 mV (vs RHE) for ORR and OER, respectively. The peak power density of ZAB equipped with the CoNi-NC catalyst was calculated to be 194 mW cm-2. The present strategy for the synthesis of bifunctional electrocatalysts with dual active sites offers prospects for developing electrochemical energy storage and conversion systems.
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MEDLINE
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2023
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Article