Carbonized polymer dots modified ZnIn2S4 microspheres for visible-light-driven hydrogen evolution promotion performance.

To effectively separate electron-hole pairs produced by light, a heterojunction arrangement can be employed, thereby improving photocatalytic efficiency. In this study, a simple hydrothermal process is used to manufacture carbonized polymer dots/ZnIn2S4 (CPDs/ZIS) heterostructure, which enhances the light absorption and charge carrier lifetime in comparison to bare ZnIn2S4 (ZIS). Upon irradiation with visible light, the 3-CPDs/ZIS composite generates hydrogen at a rate of 133 µmol g-1 h-1, which is 8.9 times faster than that of pure ZIS. The addition of CPDs can increase the range of light that can be absorbed, extend the service life of the optical charge, increase the specific surface area, and promote charge separation and transmission, which could effectively accelerate the photocatalytic reduction reaction. The presence of CPDs results in the introduction of multiple transition energy states and a decrease in the H* adsorption free energy, which enhances the hydrogen evolution activity according to the theoretical calculation findings of density functional theory (DFT) and Gibbs free energy of the hydrogen evolution process. Combining theoretical calculations and experimental results, a direct Z-type heterojunction mechanism is proposed for the hydrogen evolution promotion effectiveness of CPDs/ZIS under visible light.