Photoinduced Difunctionalization of Diazenes Enabled by N-N Radical Coupling.
Org Lett
; 25(36): 6671-6676, 2023 Sep 15.
Article
em En
| MEDLINE
| ID: mdl-37642680
ABSTRACT
In this study, a metal-free difunctionalization strategy for diazenes was developed using a range of bifunctionalization reagents. This strategy involves a unique N(sp3)-N(sp2) radical coupling between the hydrazine radical and the imine radical. More than 30 triazane core motifs were constructed by installing imines and various functional groups, including alkyl, phenyl, cyanoalkyl, and sulfonyl groups, on both ends of the nitrogen-nitrogen bond of diazenes in an efficient manner.
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MEDLINE
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En
Ano de publicação:
2023
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Article