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Complexation of Am(III) and Eu(III) with DRAPA (N,N-dialkyl-6-amide-pyridine-2-carboxylic acid).
Xu, Chao; Liu, Tingting; Liu, Qian; Yang, Suliang; Li, Dingming; Tian, Guoxin.
Afiliação
  • Xu C; College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang 150001, China. tianguoxin@hrbeu.edu.cn.
  • Liu T; College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang 150001, China. tianguoxin@hrbeu.edu.cn.
  • Liu Q; Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China. gtian@ciae.ac.cn.
  • Yang S; Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China. gtian@ciae.ac.cn.
  • Li D; Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China. gtian@ciae.ac.cn.
  • Tian G; Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China. gtian@ciae.ac.cn.
Dalton Trans ; 52(43): 15669-15671, 2023 Nov 07.
Article em En | MEDLINE | ID: mdl-37667654
The similarity of the coordination chemistry of Am(III) and Eu(III) and two homologous tridentate ligands, N,N-di-2-ethylhexyl-6-amide-pyridine-2-carboxylic acid (DEHAPA, HL') in solvent extraction and N,N-dimethyl-6-amide-pyridine-2-carboxylic acid (DMAPA, HL) in aqueous solution and in the solid state, is revealed structurally and spectroscopically with complexes ML'3 (org), ML3 (aq) and ML3 (s), respectively.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article