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Controlled Encapsulation of Gold Nanoparticles into Zr-Metal-Organic Frameworks with Improved Detection Limitation of Volatile Organic Compounds via Surface-Enhanced Raman Scattering.
Lam, Phuc Khanh; Liao, Jian-Jie; Lin, Miao-Chun; Li, Yu-Hsiu; Wang, Tsu-Hao; Huang, Hsin-Kai; Hsu, Yu-An; Hsieh, Hao-Ying Patterson; Kuan, Pu-Yun; Chen, Ching-Tien; Hao, Guo-Xiu; Tsung, Chia-Kuang; Wu, Kevin C-W; Sutka, Andris; Kinka, Martynas; Chou, Lien-Yang; Shieh, Fa-Kuen.
Afiliação
  • Lam PK; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Liao JJ; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Lin MC; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Li YH; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Wang TH; School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.
  • Huang HK; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Hsu YA; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Hsieh HP; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Kuan PY; Fudan High School, Taoyuan 32449, Taiwan.
  • Chen CT; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Hao GX; Department of Chemistry, National Central University, Taoyuan 32001, Taiwan.
  • Tsung CK; Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan.
  • Wu KC; School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.
  • Sutka A; Boston College Chemistry Department, Merkert Chemistry Center, 2609 Beacon Street, Chestnut Hill, Massachusetts 02467, United States.
  • Kinka M; Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan.
  • Chou LY; Institute of Biomedical Engineering & Nanomedicine, National Health Research Institute, Keyan Road, Zhunan, Miaoli City 350, Taiwan.
  • Shieh FK; Institute of Materials and Surface Engineering, Faculty of Materials Science and Applied Chemistry, Riga Technical University, Paula Valdena 3/7, Riga 1048, Latvia.
Inorg Chem ; 62(37): 14896-14901, 2023 Sep 18.
Article em En | MEDLINE | ID: mdl-37678159
ABSTRACT
Volatile organic compounds (VOCs) have harmful effects on human health and the environment but detecting low levels of VOCs is challenging due to a lack of reliable biomarkers. However, incorporating gold nanoparticles (Au NPs) into metal-organic frameworks (MOFs) shows promise for VOC detection. In this study, we developed nanoscale Au@UiO-66 that exhibited surface-enhanced Raman scattering (SERS) activity even at very low levels of toluene vapors (down to 1.0 ppm) due to the thickness of the shell and strong π-π interactions between benzenyl-type linkers and toluene. The UiO-66 shell also increased the thermal stability of the Au NPs, preventing aggregation up to 550 °C. This development may be useful for sensitive detection of VOCs for environmental protection purposes.
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Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Diagnostic_studies Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Diagnostic_studies Idioma: En Ano de publicação: 2023 Tipo de documento: Article