Formation of dichloroacetic acid and dichloroacetamide from phenicol antibiotic abatement during ozonation and post-chlor(am)ination.
Water Res
; 245: 120600, 2023 Oct 15.
Article
em En
| MEDLINE
| ID: mdl-37713791
ABSTRACT
This study investigated the formation of dichloroacetamide (DCAM) and dichloroacetic acid (DCAA) from the abatement of three phenicol antibiotics (PABs, chloramphenicol, thiamphenicol, and florfenicol) during ozonation and post-chlor(am)ination. Results show that the three PABs have a low ozone reactivity (kO3 = 0.11â0.12 M-1 s-1), and therefore are mainly abated through the hydrogen abstraction mechanism by hydroxyl radicals (â¢OH) during ozonation. During PAB degradation, the carboxamide moiety in the parent molecules can be cleaved off by â¢OH attack and thus gives rise to DCAM. The formed DCAM can then be further oxidized by O3 and/or â¢OH to DCAA as a more stable transformation product (TP). When the three PABs were adequately abated (abatement efficiency of â¼82 %â95 %), the molar yields of DCAM and DCAA were determined to be 2.79 %â4.71 % and 32.9 %â37.2 %, respectively. Furthermore, post-chloramination of the ozonation effluents increased the yields of DCAM and DCAA slightly to 4.20 %â6.45 % and 39.0 %â41.1 %, respectively. In comparison, post-chlorination eliminated DCAM in the solutions, but significantly increased DCAA yields to â¼100 % due to the further conversion of DCAM and other ozonation TPs to DCAA by chlorine oxidation. The results of this study indicate that high yields of DCAM and DCAA can be generated from PAB degradation during ozonation, and post-chlorination and post-chloramination will result in very different fates of DCAM and DCAA in the disinfected effluent. The formation and transformation of DCAM and DCAA during PAB degradation need to be taken into account when selecting multi-barrier treatment processes for the treatment of PAB-containing water.
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MEDLINE
Assunto principal:
Ozônio
/
Poluentes Químicos da Água
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Purificação da Água
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article