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Metal-free electrocatalytic nanocomposites of poly azovan blue-decorated graphitic carbon nitride for simultaneously sensing paracetamol and 4-aminophenol.
Sekar, Sankar; Yun, Ji-Seop; Lee, Sejoon.
Afiliação
  • Sekar S; Department of Semiconductor Science, Dongguk University-Seoul, Seoul, 04620, Republic of Korea; Quantum-Functional Semiconductor Research Center, Dongguk University-Seoul, Seoul, 04620, Republic of Korea.
  • Yun JS; Department of Semiconductor Science, Dongguk University-Seoul, Seoul, 04620, Republic of Korea; Quantum-Functional Semiconductor Research Center, Dongguk University-Seoul, Seoul, 04620, Republic of Korea.
  • Lee S; Department of Semiconductor Science, Dongguk University-Seoul, Seoul, 04620, Republic of Korea; Quantum-Functional Semiconductor Research Center, Dongguk University-Seoul, Seoul, 04620, Republic of Korea. Electronic address: sejoon@dongguk.edu.
Environ Res ; 239(Pt 1): 117293, 2023 Dec 15.
Article em En | MEDLINE | ID: mdl-37816424
Excessive consumption of paracetamol (PA) and 4-aminophenol (4-AP) can have harmful effects on the human body. This study developed a novel electroanalytical technique that utilizes the nanocomposites of poly azovan blue (PAB)-decorated graphitic carbon nitride (g-C3N4), deposited onto a screen-printed carbon electrode (SPCE), for the concurrent sensing of PA and 4-AP. The fabricated g-C3N4@PAB/SPCE exhibited exceptional synergistic effects, such as a high active electrochemical surface area and excellent electron transfer properties. The electrochemical behavior of g-C3N4@PAB/SPCE for simultaneous PA and 4-AP sensing was evaluated in the linear dynamic ranges of 0.08-75 and 0.05-90 µM, with the detection limits (S/N = 3) of 0.011 and 0.016 µM and sensitivities of 2.974 and 2.857 µA/µM/cm-2 for PA and 4-AP, respectively. Additionally, g-C3N4@PAB/SPCE showed long-term stability, high reproducibility (RSD = 2.17%, n = 4), and superior anti-interference capabilities. Finally, when g-C3N4@PAB/SPCE was tested for simultaneously sensing both PA and 4-AP in tap water and artificial urine models, it exhibited satisfactory recoveries, demonstrating its potential use for various industrial and clinical applications.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Nanocompostos / Acetaminofen Limite: Humans Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Nanocompostos / Acetaminofen Limite: Humans Idioma: En Ano de publicação: 2023 Tipo de documento: Article